Question

What are quantum numbers? And how many are there?

Asked by: Sharma

Answer

Quantum numbers arise when we try to find the solution of the Schrödinger equation. Depending on the complexity the situation, determines how many quantum numbers there will be.

For example for a harmonic oscillator (a 1-D particle pond by a potential V=1/2kx^2 ) we only get one quantum number n and it represents the energy level of the harmonic oscillator. E=nhf.

For the 3-D one electron atom we get three n,l and ml. These represent the energy level, angular momentum and the angular moment in the z direction.

Another quantum number is ms and it represents the spin of the electron.

So as you can see as we extend the complexity of the situation, we get quantum numbers for everything, which is measurable.

Answered by: Jay, Australia


Answer

Each electron has a set of four numbers, called quantum numbers, that specify it completely; no two electrons in the same atom can have the same four. That's a more precise statement of the Pauli exclusion principle.

Primary quantum number, which is given the symbol n,n tells you which of the "main" energy levels you're in.

The second quantum number is known as l. A value of l=0 corresponds to s, l=1 is p, l=2 is d, and so forth.

The third is magnetic quantum number m. l, along with n and the third quantum number, m, is responsible for determining the shape of an electron's probability cloud.

The fourth quantum number, s, does indeed pertain to an electron's spin. s only has two possible values+1/2 or-1/2.s= +1/2 means "spin up" and s= -1/2 means "spin down."

Within the level given by a particular n, l can take on only integer values from 0 to n-1.So when n is 1, l can only be 0, and that's why the first row has only s states. Then when n=2, l can be either 0 or 1, and that gives you s and p. Given a particular l, m is entitled to be any integer from minus l up to l. For example, when l=1, m can be -1, 0, or 1; those are your three p states. For a given l, there are 2l+1 different values of m.

Answered by: Yash Kumar, B.S., Physics graduate student, India

Search

Loading



Sponsors

USC University of Southern California Dornsife College Physics and Astronomy Department McMaster University Physics and Astronomy Department

Science Quote

'The atomic bomb ... made the prospect of future war unendurable. It has led us up those last few steps to the mountain pass; and beyond there is different country.'

J. Robert Oppenheimer
(1904-1966)

Deal of the Day

Image of Black Hawk Wolf RC Helicopter. Click on this image for more info. Black Hawk Wolf RC Helicopter
Regular Price: $39.99
Today's Price: $14.00
Easy to fly 3 channel mini remote-controlled helicopter. Buy it now! Deal ends at midnight!

Top Selling

Here are our physics & astronomy bestsellers:
Mini Plasma Ball
Slide Making Kit
The Ultimate Geek Pen
Top Secret - Spinning Top
Thermodynamic Drinking Bird
Wood Grain Newtons Cradle
Deluxe 3D Mirascope
Solar Radiometer
Periscope
Solar Science 4M Kit