Why does oil float to the top in liquid if you try to mix it with the liquid?
Asked by: Rachel Ginsberg
I think there are 2 questions here. The first is why
oil and water don't mix. The second is why oil rises,
as opposed to sinking or staying in place.
First question. There is an old saying in chemistry
that like dissolves like. What this means is that
a substance tends to dissolve in another substance if the
molecules of the 2 substances have similar electric dipole moments. Think of an
electric dipole like you think of a magnet. The magnet has a north and south pole,
and south end of one magnet is attracted to the north end of another magnet, and
vice versa. The electric dipole has a positively charged end and a negatively
charged end. The magnitude of the positive charge can be greater than that of the
negative charge, or vice versa. The difference between the magnitudes of the 2
charges and the distance between them determines the moment or strength of the
dipole. In general, dipoles with similar strengths dissolve in each other more
readily than dipoles with very different strengths. Oil (as in hydrocarbon-based
oils) and water have very different dipole moments, so oil and water do not readily
dissolve in each other.
The second part of the answer has to do with a force
called the buoyancy force. This is the force that
causes some objects to float in water. Suppose you want to dissolve 1 cubic cm of
oil in water. For this to happen, the oil has to displace 1 cubic cm of water. The
buoyancy force on the oil is equal to the weight of that 1 cubic cm of water. Oil
is less dense than water, so 1 cubic cm of oil weighs less than 1 cubic cm of water.
Therefore, the upward buoyancy force on the oil, which is equal to the weight of
water displaced, is greater than the downward force of gravity on the oil, also
known as the weight of the oil. This inequality of forces causes the oil to rise in
the water. If the
oil were denser than the water, the oil's weight
(the downward force) would exceed the buoyancy force
(the upward force), and the oil would sink in the water.
Answered by: Philip Zell, Ph.D. Physics, ACT, Inc.
'I believe there is no philosophical high-road in science, with epistemological signposts. No, we are in a jungle and find our way by trial and error, building our road behind us as we proceed.'