Water boiling on a pan get its heat as a result of conduction from the pan's surface to the water.
In film boiling the process of heat transfer is quite different.
Water exposed to atmospheric pressure boils at approximately 100 degrees Celsius. Water below the
surface is not directly exposed to the atmosphere and can remain a liquid as it superheats above
this temperature. At a sufficiently high temperature the water below would vaporize and form a gas
layer that supports the body of water above. As a result heat transfer from the heated surface to
the water occurs mainly through radiation. This process is known as film boiling.
If you take a pot of water and heat it on a stove in your kitchen, film boiling would be impossible
to achieve. You may have more success on a laboratory burner. But the phenomena can be observed in
your kitchen.
If you heat a pan sufficiently and sprinkle water on it you may see the drops of water bead up and
'dance' around on the surface. This occurs because as the drop hits the pan a layer of vapor is
formed underneath and this supports the water droplet. The vapor continually escapes to the sides
and is replenished by the water drop above until it disappears.
Answered by: David Latchman, B.Sc. Physics, University of the West Indies
'To myself I seem to have been only like a boy playing on the seashore, and diverting myself in now and then finding a smoother pebble or a prettier shell than ordinary, whilst the great ocean of truth lay all undiscovered before me.'