How did thermal blackbody radiation spectrum not fit classical physics and what was done about it?

Asked by:
Kirstie

Answer

You are referring to the so-called 'ultraviolet catastrophe', in which classical physics predicted that the electromagnetic spectrum emitted by warm objects should show an increasing intensity at higher and higher frequencies. This impossible outcome of course disagreed with experimental evidence, and was eventually explained by postulating that energy could only be emitted in discrete packets of definite size. Just as you can only pay cash in increments of 1 cent (U.S.), nature has a smallest unit of energy which is not infinitely divisible.
Assuming that energy could not exist at arbitrary levels, but instead exists in packages of discrete sizes, the spectrum calculation changed to one that agrees with observations. As temperature increases, radiation emission reaches a peak at higher and higher frequencies but decreases at frequencies beyond that peak.
It was the attempt to explain the 'ultraviolet catastrophe' that lead to the development of quantum physics and understanding of the statistical rather than absolute outcomes of
matter/energy interactions.
Answered by:
Paul Walorski, B.A., Part-time Physics/Astronomy Instructor

Classical mechanics could not accurately predict the spectrum of radiation emitted by a heated body. In fact, it predicted that a hot body should radiate an infinite amount of energy.
This means that, according to classical theory, if we switch on an oven, the amount of energy contained in radiation waves inside of it will be infinite. And that's bad news for the chips we put inside...
The electromagnetic radiation we are considering is wave-like in character and the waves that are produced in the oven must fit perfectly. They have a whole number of peaks and troughs in the same way that vibrations on a plucked string fit the length of the string nicely. Even with this restriction, there are still an infinite number of waves that can fit inside the oven - a wave with one oscillation, a wave with two oscillations, a wave with three, etc. Here's the trouble - classical mechanics predicts that each of these waves will exist and that each will contribute the same amount of energy to the total in the oven. That's a total of .... um, .... lots.
It was Max Planck that solved this problem in 1900. He suggested that each wave has an intrinsic, associated energy (totally independent of the temperature of the oven). Waves with smaller wavelengths (and therefore higher frequencies) have higher energies. He gave the following equation to determine the energy of a wave:
Energy of a wave = (Planck's constant) * (Frequency of the wave)
This idea is familiar to us today, we know that x-rays have more energy than rays of light, which in turn are more powerful than radio waves. These are all examples of electromagnetic radiation - but with different frequencies, and therefore, according to Planck's idea, different energies.
This solved the problem of blackbody radiation in the following way. Because each wave has a particular energy, there are only a finite number of waves that have an energy that is less than that associated with the oven. Not all waves that fit in the oven actually exist - there are some who require more energy than is available. If a particular wavelength has too high an energy threshold, it doesn't contribute anything - it doesn't 'wave' at all! This means that the total number of waves (and therefore the total energy) in the oven is finite, and even more exiting, it fits the spectrum discovered experimentally.
It was Einstein who realised what Planck was really doing here. Beneath the concept that each wave has an associated energy is a deeper one - that electromagnetic waves can be 'quantisized'. The idea is that waves can only carry particular values of energy because they actually arrive as particles, each with a specific energy value. It isn't possible for half a particle to arrive ! Solving the blackbody dilemma was therefore one of the first steps to quantum theory - this is ultimately what scientists had to do about the blackbody conflict between theory and experimental evidence - they embarked upon a new theory altogether !
Answered by:
Sally Riordan, M.A., Management Consultant, London

'Physics is mathematical not because we know so much about the physical world, but because we know so little; it is only its mathematical properties that we can discover.'