The center of the sun is the hottest part (at around 15 million Kelvins, or 27 million degrees Fahrenheit). The temperature then drops to 5,800 K (10,000 degrees F) at the visible surface, although the corona (the part just above the surface, where solar flares are), can get much hotter (2 million K, or 3.6 million degrees F).
I found this information and tons of really neat stuff (pictures, movies, etc.) at http://sohowww.nascom.nasa.gov/ , which is the homepage for NASA's SOHO (SOlar and Heliospheric Observatory) project. For a good intro, click on "Classroom" (on the left hand side, under the "RESOURCES" heading), and then on the section for "The Sun 101" course.
Gregory Ogin, Physics Undergraduate Student, UST, St. Paul, MN
'You cannot hope to build a better world without improving the individuals. To that end each of us must work for his own improvement, and at the same time share a general responsibility for all humanity, our particular duty being to aid those to whom we think we can be most useful.'